| 15154795 |
Gilbertson JD, Szymczak NK, Tyler DR: H2 activation in aqueous solution: formation of trans-[Fe (DMeOPrPE) 2H (H2)]+ via the heterolysis of H2 in water. Inorg Chem. 2004 May 31;43(11):3341-3.
The water-soluble iron phosphine complex trans-Fe (DMeOPrPE)(2) Cl (2) (DMeOPrPE = 1,2-bis (bis (methoxypropyl) phosphino) ethane) reacts with H (2) in water to produce trans-[Fe (DMeOPrPE)(2) H (H (2))](+) and H (+). The product is a water-soluble eta (2)-H (2) metal hydride complex, formed via the heterolysis of coordinated H (2) in water. |
81(1,1,1,1) |